WSEAS Transactions on Environment and Development


Print ISSN: 1790-5079
E-ISSN: 2224-3496

Volume 14, 2018

Notice: As of 2014 and for the forthcoming years, the publication frequency/periodicity of WSEAS Journals is adapted to the 'continuously updated' model. What this means is that instead of being separated into issues, new papers will be added on a continuous basis, allowing a more regular flow and shorter publication times. The papers will appear in reverse order, therefore the most recent one will be on top.


Volume 14, 2018



A Comparison of Two Methods for Determination of K and Na Release Behavior from a Single Biomass Pellet during Combustion

AUTHORS: Nerijus Striūgas, Marius Sadeckas, Peter Sommersacher, Stefan Retschitzegger

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ABSTRACT: This study focuses on the measurement of spontaneous alkali release from biomass pellet during combustion in order to compare two different techniques. Flame emission spectrometry (FES) was used for optical detection of chemiliuminescence spectra of selected metals using optical bandpass filters mounted on ICCD (Intensified Charge Coupled Device) camera Andor iStar DH734. To gain better understanding about alkali-metal release processes and to compare obtained results, test runs with a single particle reactor (SPR) connected with an inductively coupled plasma mass spectrometer (ICP-MS) have been performed. By coupling the reactor to an ICP-MS, time-resolved release profiles of relevant aerosol forming elements (K, Na) were determined and compared with those obtained by FES experiments.

KEYWORDS: biomass, pellet, straw, wood, combustion, alkali metals, FES, ICP-MS

REFERENCES:

[1] Leffler, T.; Brackmann, C.; Berg, M.; Li, Z. S.; Aldén, M. ON-Line Alkali Measurement for Fuel Quality Control in Biomass-Operated Boilers. Ind. Combust. 2016, 2016 (1).

[2] Niu, Y.; Tan, H.; Hui, S. Ash-Related Issues during Biomass Combustion: Alkali-Induced Slagging, Silicate Melt-Induced Slagging (Ash Fusion), Agglomeration, Corrosion, Ash Utilization, and Related Countermeasures. Progress in Energy and Combustion Science. 2016, pp 1–61.

[3] Sadeckas, M.; Striūgas, N.; Andriūnas, P.; Praspaliauskas, M.; Rabaçal, M.; Costa, M. Spontaneous emission measurements of selected alkali radicals during the combustion of a single biomass pellet. 2018. Energy & Fuels Article

[4] Navakas, R.; Saliamonas, A.; Striūgas, N.; Džiugys, A.; Paulauskas, R.; Zakarauskas, K. Effect of Producer Gas Addition and Air Excess Ratio on Natural Gas Flame Luminescence. Fuel 2018, 217, 478–489.

[5] Sommersacher, P.; Kienzl, N.; Brunner, T.; Obernberger, I. Simultaneous Online Determination of S, Cl, K, Na, Zn, and Pb Release from a Single Particle during Biomass Combustion. Part 2: Results from Test Runs with Spruce and Straw Pellets. Energy and Fuels 2016, 30 (4), 3428–3440.

[6] Sommersacher, P.; Brunner, T.; Obernberger, I.; Kienzl, N.; Kanzian, W. Application of Novel and Advanced Fuel Characterization Tools for the Combustion Related Characterization of Di Ff Erent Wood / Kaolin and Straw / Kaolin Mixtures. 2013.

[7] Johansen, J. M.; Jakobsen, J. G.; Frandsen, F. J.; Glarborg, P. Release of K, Cl, and S during Pyrolysis and Combustion of High-Chlorine Biomass. Energy and Fuels 2011, 25 (11), 4961–4971.

[8] Knudsen, J. N.; Jensen, P. A.; Dam-Johansen, K. Transformation and Release to the Gas Phase of Cl, K, and S during Combustion of Annual Biomass. Energy and Fuels 2004, 18 (5), 1385–1399.

[9] Paulauskas, R.; Džiugys, A.; Striugas, N. Experimental Investigation of Wood Pellet Swelling and Shrinking during Pyrolysis. Fuel 2015, 142, 145–151.

WSEAS Transactions on Environment and Development, ISSN / E-ISSN: 1790-5079 / 2224-3496, Volume 14, 2018, Art. #48, pp. 451-456


Copyright © 2018 Author(s) retain the copyright of this article. This article is published under the terms of the Creative Commons Attribution License 4.0

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